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The production of O(1D) from dissociative recombination of O2(+)The results of large scale ab initio calculations of the rates for production of O(1D) by dissociative combination of O2(+) are presented for electron temperatures in the range 100 to 3000 K. A 1-delta-u state is the dominant dissociative route from v = 0 and a 3-sigma-u(-) state is the most important route from v = 1 and v = 2. The calculated total rate for O(1D) production from v = 0 is 2.21(+0.21,-0.24) x 10(-7) x (T sub e/300) exp -.46 near room temperature. The v = 1 and v = 2 rates are about 17% and 47% smaller respectively, than the v = 0 rate at 300 K.
Document ID
19870016397
Acquisition Source
Legacy CDMS
Document Type
Contractor Report (CR)
Authors
Guberman, Steven L. (Harvard-Smithsonian Center for Astrophysics Cambridge, MA, United States)
Date Acquired
September 5, 2013
Publication Date
January 1, 1987
Subject Category
Atomic And Molecular Physics
Report/Patent Number
NASA-CR-181145
NAS 1.26:181145
Accession Number
87N25830
Funding Number(s)
CONTRACT_GRANT: NSF ATM-86-16776
CONTRACT_GRANT: NCC2-308
CONTRACT_GRANT: AF-AFOSR-0109-84
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.

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